Analysis of the Experimental Production Possibility of Polysubstituted Crystals with M-type Hexaferrite Structure

D. E. Zhivulin, D. A. Vinnik, O. V. Zaitseva

Abstract


The analysis of experimental studies on the substituted single crystals with the structure of M-type hexaferrite production is carried out. The results demonstrate the possibility of attaining sufficiently high substitution degrees even for the cases of using single substituent of iron atoms. The results of the analysis make it possible to expect that substituents number increasing, which will be accompanied by the mixing entropy increasing and, as a consequence, a the solid phase Gibbs energy decreasing, will contribute to the structures stabilization with an even greater substitution level. In the course of experimental work on obtaining samples of multicomponent (highly entropic) crystals with the structure of M-type hexaferrite, the methods, methods and equipment described in the text of this article that were previously used to obtain single crystals of BaFe12-xMeхO19 with one substitute atoms of iron.

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References


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DOI: http://dx.doi.org/10.24892/RIJIE/20190104

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